Millathane® E40



Millathane E40 is a sulfur or peroxide curable polyether polyurethane rubber for the production of rollers, belts seals, gaskets, and other molded parts which require excellent abrasion resistance, low temperature performance, hydrolytic stability and high mechanical strength.

PRODUCT DESCRIPTION
Chemical composition: Polyether polyurethane rubber
Specific gravity Approximately 1.07
Appearance: Clear to tan colored bales or milled sheets
Packaging: 38 lb (17.2 kg)/box bales or 50 lb (20.7 kg)/box milled sheets
Mooney Viscosity: 30 to 60 ML(1+4)/100°C bale
Mooney Viscosity:  35 to 55 ML(1+4)/100°C milled sheets
Storage stability 2 years under dry and cool conditions
 


Processing
Millathane E40 is processed by techniques that are common to the rubber industry. Compounds can be mixed on an open mill or in an internal mixer. Millathane E40 has been designed not to crystallize at ambient temperatures, which allows mixing “right out of the box”. Due to the toughness of E40, a two-pass mix using an internal mixer is recommended. Very often a masterbatch can be mixed and followed by addition of curatives on a two-roll mill. Molded articles can be produced through compression, transfer or injection molding. Injection molding Millathane E40 provides very short cycle times, excellent flow and de-molding. Millathane E40 can be cured in steam autoclaves (protected from direct contact with the steam) and is suitable for large roller, hose or belting applications. Calendered sheets can be press-cured or rotational-cured.

Properties
Vulcanizates based on Millathane E40 offer a very good abrasion resistance, excellent low temperature properties, excellent hydrolytic stability, high mechanical strength and outstanding dynamic properties. Millathane E40 maintains its properties nearly unchanged over a wide range of temperatures and makes it a perfect choice for rollers seals, gaskets, CV-boots, dust covers, mounts and bearings for the automotive industry and for many other hydraulic or pneumatic applications. It is particularly suited for production of injection molded rollers for office machines due to its ability to bond to metal shafts.

Compounding
Compound design of Millathane E40 follows the typical pattern of formulating for oil resistant polymers. Reinforcing fillers like carbon black or fumed silica increase the mechanical strength. Sulfur cure is accomplished with the use of MBTS, MBT zinc stearate and Thanecure® ZM. A variety of dialkyl peroxides like dicumyl peroxide, t-butyl cumyl peroxide, 2, 5-dimethyl-2,5-di (t-butylperoxy) hexane etc. can be used as vulcanization chemicals. The use of co-agents like triallylcyanurate (TAC) results in a very high crosslinking density and improves the compression set. Adding various plasticizers and softeners, especially coumarone indene resins and TP-95 (DBEEA: Dibutoxyethoxyethyl adipate), improve processibility.

Vulcanization Conditions
Compounds based on Millathane E40 can be vulcanized at temperatures between 140 - 165ºC, depending on the cure system and the thickness of the part.

Formulation Example

Millathane E40 100.0
Zinc Stearic           0.5
N220 Black 20.0
Cumar P10 (coumarone indene resin) 8.0
AC Poly 617A (polyethylene) 1.0
MBTS 4.0
MBT 2.0
Thanecure® ZM 1.0
Sulfur 2.0
Total 138.5
   
Press Cure 15'/155ºC
Durometer A 58
Tensile Strength, MPa 23.4
100% Modulus, MPa 1.5
200% Modulus, MPa 3
300% Modulus, MPa 5.7
Elongation, % 595
Tear Die C, kN/m 22.6
   
Resilience, % 42
DIN Abrasion, mm³ loss 109
Compression set, % 70hr/70ºC 68
Coefficient of Friction ASTM D1894 3

Please contact us for additional information:

Millathane® Customer Service
Nina Manee at (800) 237-7634 x1348 or (727) 573-7676 x1348



Millathane® Technical Service:
Tom Jablonowski at (800) 237-7634 x1238 or (727) 573-7676 x1238

 

Millathane® Home
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Thanecure
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*Millathane 5004 and Millathane CM were formerly known as Vibrathane 5004 and Adiprene CM. Adiprene® and Vibrathane® are registered trademarks of Chemtura Corp.

 

 
 

 

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