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Millathane® E40
Millathane E40 is a sulfur or peroxide curable
polyether polyurethane rubber for the production of rollers, belts seals,
gaskets, and other molded parts which require excellent abrasion resistance,
low temperature performance, hydrolytic stability and high mechanical
strength.
| PRODUCT DESCRIPTION |
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Chemical composition: |
Polyether polyurethane rubber |
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Specific gravity |
Approximately 1.07 |
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Appearance: |
Clear
to tan colored bales or milled sheets |
| Packaging: |
38 lb (17.2 kg)/box bales
or 50 lb (20.7 kg)/box milled sheets |
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Mooney Viscosity: |
30 to
60 ML(1+4)/100°C bale |
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Mooney Viscosity: |
35
to 55 ML(1+4)/100°C milled sheets |
| Storage stability |
2
years under dry and cool conditions
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Processing
Millathane E40 is processed by techniques that are common to the
rubber industry. Compounds can be mixed on an open mill or in an internal
mixer. Millathane E40 has been designed not to crystallize at ambient
temperatures, which allows mixing “right out of the box”. Due to the
toughness of E40, a two-pass mix using an internal mixer is recommended.
Very often a masterbatch can be mixed and followed by addition of curatives
on a two-roll mill. Molded articles can be produced through compression,
transfer or injection molding. Injection molding Millathane E40 provides
very short cycle times, excellent flow and de-molding. Millathane E40 can be
cured in steam autoclaves (protected from direct contact with the steam) and
is suitable for large roller, hose or belting applications. Calendered
sheets can be press-cured or rotational-cured.
Properties
Vulcanizates based on Millathane E40 offer a very good abrasion resistance,
excellent low temperature properties, excellent hydrolytic stability, high
mechanical strength and outstanding dynamic properties. Millathane E40
maintains its properties nearly unchanged over a wide range of temperatures
and makes it a perfect choice for rollers seals, gaskets, CV-boots, dust
covers, mounts and bearings for the automotive industry and for many other
hydraulic or pneumatic applications. It is particularly suited for
production of injection molded rollers for office machines due to its
ability to bond to metal shafts.
Compounding
Compound design of Millathane E40 follows the typical pattern of
formulating for oil resistant polymers. Reinforcing fillers like carbon
black or fumed silica increase the mechanical strength. Sulfur cure is
accomplished with the use of MBTS, MBT zinc stearate and Thanecure® ZM. A
variety of dialkyl peroxides like dicumyl peroxide, t-butyl cumyl peroxide,
2, 5-dimethyl-2,5-di (t-butylperoxy) hexane etc. can be used as
vulcanization chemicals. The use of co-agents like triallylcyanurate (TAC)
results in a very high crosslinking density and improves the compression
set. Adding various plasticizers and softeners, especially coumarone indene
resins and TP-95 (DBEEA: Dibutoxyethoxyethyl adipate), improve
processibility.
Vulcanization Conditions
Compounds based on Millathane E40 can be vulcanized at temperatures between
140 - 165ºC, depending on the cure system and the thickness of the part.
Formulation Example
| Millathane E40 |
100.0 |
| Zinc Stearic
|
0.5 |
| N220 Black |
20.0 |
| Cumar P10 (coumarone indene
resin) |
8.0 |
| AC Poly 617A (polyethylene) |
1.0 |
| MBTS |
4.0 |
| MBT |
2.0 |
| Thanecure® ZM |
1.0 |
| Sulfur |
2.0 |
| Total |
138.5 |
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| Press Cure 15'/155ºC |
| Durometer A |
58 |
| Tensile Strength, MPa |
23.4 |
| 100% Modulus, MPa |
1.5 |
| 200% Modulus, MPa |
3 |
| 300% Modulus, MPa |
5.7 |
| Elongation, % |
595 |
| Tear Die C, kN/m |
22.6 |
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| Resilience, % |
42 |
| DIN Abrasion, mm³ loss |
109 |
| Compression set, % 70hr/70ºC |
68 |
| Coefficient of Friction ASTM D1894 |
3 |
Please contact us for
additional information:
Millathane®
Customer Service
Nina Manee at (800) 237-7634 x1348 or (727) 573-7676 x1348
Millathane® Technical Service:
Tom Jablonowski at
(800) 237-7634 x1238 or (727) 573-7676 x1238
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